I saw this on the shelf at Barnes and Noble in the “Travel” section. Thrilling Cities was a travelogue written by Ian Fleming in 1963.
He had been writing the Bond novels for a decade and the films had just become very popular. The Sunday Times flew Fleming around the world to visit 13 cities to write about them and play off the popularity of James Bond.
The Wikipedia page has very detailed history of the book and Fleming’s travels (which he reportedly hated).