Here’s a short video about Daniel Craig’s screen test for Bond (it says 2006, but Casino Royale was released in 2006, so it had to be earlier than that). There’s a voiceover from Barbara Broccoli and Michael Wilson about how much they wanted Craig for the role.
Then, towards the end, you see and hear the scene they’re doing — it’s the “I’m the money” scene between Vesper and Bond (”…every penny of it”) that was on the train in the film but is being done on a hotel room set for the screen test.
Vesper is played by someone other than Eva Green. I’m not sure who is playing Craig’s haircut.